Ustad Bade Ghulam Ali Khan had toured Kabul, Afghanistan and, on the way back to India, Ghulam Ali's father requested the Ustad to take his son as a disciple.

Ghulam Ali encountered Ustad Bade Ghulam Ali Khan, for the first time, when he was in his early teens. Ghulam Ali had always been listening to Khan since childhood. His name 'Ghulam Ali' was given by his father, a great fan of Bade Ghulam Ali Khan who, in the past, used to live in Lahore. His sons Aamir Ghulam Ali and Nazar Ali Abbas are also musicians. In a news item reported in 2015, Ghulam Ali has said that he won't perform in India until situation is right for music.He, however, assured that he will visit India when ‘the atmosphere is right.’ He said that he does not want to be used for political mileage. After this cancellation, he performed at Lucknow, India., New Delhi and in Trivandrum, and Kozhikode, Kerala, India. After this, he received invitations from Delhi Chief Minister Arvind Kejriwal, West Bengal Chief Minister Mamata Banerjee and Uttar Pradesh Chief Minister Akhilesh Yadav. In 2015, due to protest by Shiv Sena at Mumbai, his concert was cancelled. He was married to Afsana Ali and has a daughter Manjari Ghulam Ali. His recent album 'Hasratein' was nominated in the Best Ghazal Album category at Star GIMA Awards 2014. His famous ghazals are Chupke Chupke Raat Din, Kal Chaudhvin Ki Raat Thi, Hungama Hai Kyon Barpa, Chamakte Chand Ko, Kiya Hai Pyar Jisé, May Nazar Sé Pee Raha Hoon, Mastana Peeyé, Yé dil yé pagal dil, Apni Dhun Mein Rehta Hoon a ghazal by Nasir Kazmi, 'Ham Ko Kiske Gham Ne Maara'.

Many of his hit ghazals have been used in Bollywood movies.

Highly popular in Pakistan, India, Afghanistan, Nepal, Bangladesh, as well as among South Asian diaspora in the US, the UK and the Middle Eastern countries. His style and variations in singing Ghazals has been noted as unique, as he blends Hindustani classical music with ghazals, unlike any other ghazal singer. Ghulam Ali is considered to be one of the best ghazal singers of his era. Ali was also trained by Bade Ghulam Ali's younger brothers – Barkat Ali Khan and Mubarak Ali Khan. Ghulam Ali was a disciple of Bade Ghulam Ali Khan (elder Ghulam Ali Khan). He has also been a prominent playback singer in Bollywood. Ustad Ghulam Ali ( Urdu: غُلام علی born 5 December 1940) is a Pakistani ghazal singer of the Patiala Gharana.

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